Brian M. Hoffman

Research interests

Publications

• Reduction of Substrates by Nitrogenases

  Chemical Reviews · 2020 · https://doi.org/10.1021/acs.chemrev.9b00556

• Particulate methane monooxygenase contains only mononuclear copper centers

  Science · 2019 · https://doi.org/10.1126/science.aav2572

• Beyond fossil fuel–driven nitrogen transformations

  Science · 2018 · https://doi.org/10.1126/science.aar6611

• Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

  Chemical Reviews · 2014 · https://doi.org/10.1021/cr400641x

• Nitrogenase: A Draft Mechanism

  Accounts of Chemical Research · 2013 · https://doi.org/10.1021/ar300267m

• The Yeast Iron Regulatory Proteins Grx3/4 and Fra2 Form Heterodimeric Complexes Containing a [2Fe-2S] Cluster with Cysteinyl and Histidyl Ligation

  Biochemistry · 2009 · https://doi.org/10.1021/bi901182w

• Mechanism of Mo-Dependent Nitrogenase

  Annual Review of Biochemistry · 2009 · https://doi.org/10.1146/annurev.biochem.78.070907.103812

• Climbing Nitrogenase: Toward a Mechanism of Enzymatic Nitrogen Fixation

  Accounts of Chemical Research · 2009 · https://doi.org/10.1021/ar8002128

• Substrate Interactions with the Nitrogenase Active Site

  Accounts of Chemical Research · 2005 · https://doi.org/10.1021/ar040050z

• Trapping H - Bound to the Nitrogenase FeMo-Cofactor Active Site during H 2 Evolution: Characterization by ENDOR Spectroscopy

  Journal of the American Chemical Society · 2005 · https://doi.org/10.1021/ja043596p

• 17O ENDOR Detection of a Solvent-Derived Ni−(OHx)−Fe Bridge That Is Lost upon Activation of the Hydrogenase fromDesulfovibrio gigas

  Journal of the American Chemical Society · 2001 · https://doi.org/10.1021/ja010204v

• Hydroxylation of Camphor by Reduced Oxy-Cytochrome P450cam: Mechanistic Implications of EPR and ENDOR Studies of Catalytic Intermediates in Native and Mutant Enzymes

  Journal of the American Chemical Society · 2001 · https://doi.org/10.1021/ja003583l

• Reconsideration of X, the Diiron Intermediate Formed during Cofactor Assembly in E. coli Ribonucleotide Reductase

  Journal of the American Chemical Society · 1996 · https://doi.org/10.1021/ja960399k

• Theory and Practice of Electron Transfer within Protein−Protein Complexes: Application to the Multidomain Binding of Cytochromecby CytochromecPeroxidase

  Chemical Reviews · 1996 · https://doi.org/10.1021/cr9500444

• Detection and characterization of exchangeable protons bound to the hydrogen-activation nickel site of Desulfovibrio gigas hydrogenase: a proton and deuterium Q-band ENDOR study

  Journal of the American Chemical Society · 1991 · https://doi.org/10.1021/ja00001a003

• Electron-nuclear double resonance spectroscopy of nitrogen-15-enriched phthalate dioxygenase from Pseudomonas cepacia proves that two histidines are coordinated to the [2Fe-2S] Rieske-type clusters

  Biochemistry · 1989 · https://doi.org/10.1021/bi00437a051

• Identification by ENDOR of Trp 191 as the Free-Radical Site in Cytochrome c Peroxidase Compound ES

  Science · 1989 · https://doi.org/10.1126/science.2549632

• Gated electron transfer: when are observed rates controlled by conformational interconversion?

  Journal of the American Chemical Society · 1987 · https://doi.org/10.1021/ja00255a003

• Porphyrinic molecular metals

  Accounts of Chemical Research · 1983 · https://doi.org/10.1021/ar00085a003

• Chemical, spectral, structural, and charge transport properties of the "molecular metals" produced by iodination of nickel phthalocyanine

  Journal of the American Chemical Society · 1980 · https://doi.org/10.1021/ja00542a008

• Multiple low spin forms of the cytochrome c ferrihemochrome. EPR spectra of various eukaryotic and prokaryotic cytochromes c.

  Journal of Biological Chemistry · 1977 · https://doi.org/10.1016/s0021-9258(17)32756-4

• A new class of highly conductive molecular solids: the partially oxidized phthalocyanines

  Journal of the American Chemical Society · 1977 · https://doi.org/10.1021/ja00443a070

• Synthetic oxygen carriers of biological interest

  Accounts of Chemical Research · 1975 · https://doi.org/10.1021/ar50095a004

• Electron paramagnetic resonance studies of some cobalt(II) Schiff base compounds and their monomeric oxygen adducts

  Journal of the American Chemical Society · 1970 · https://doi.org/10.1021/ja00704a010

• Coboglobins: Oxygen-Carrying Cobalt-Reconstituted Hemoglobin and Myoglobin

  Proceedings of the National Academy of Sciences · 1970 · https://doi.org/10.1073/pnas.67.2.637

Current projects

No projects listed.