Anthony L. Spek

Research interests

Publications

• checkCIF validation ALERTS: what they mean and how to respond

  Acta Crystallographica Section E Crystallographic Communications · 2019 · https://doi.org/10.1107/s2056989019016244

• PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors

  Acta Crystallographica Section C Structural Chemistry · 2014 · https://doi.org/10.1107/s2053229614024929

• Electrocatalytic CO 2 Conversion to Oxalate by a Copper Complex

  Science · 2010 · https://doi.org/10.1126/science.1177981

• Structure validation in chemical crystallography

  Acta Crystallographica Section D Biological Crystallography · 2009 · https://doi.org/10.1107/s090744490804362x

• IPr* an easily accessible highly hindered N-heterocyclic carbene

  Dalton Transactions · 2009 · https://doi.org/10.1039/b921894g

• Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution

  Proceedings of the National Academy of Sciences · 2009 · https://doi.org/10.1073/pnas.0809666106

• Determination of absolute structure using Bayesian statistics on Bijvoet differences

  Journal of Applied Crystallography · 2008 · https://doi.org/10.1107/s0021889807059870

• Crystal Structure Refinement

  Journal · 2006 · https://doi.org/10.1093/acprof:oso/9780198570769.001.0001

• Alcoholysis of Acylpalladium(II) Complexes Relevant to the Alternating Copolymerization of Ethene and Carbon Monoxide and the Alkoxycarbonylation of Alkenes: the Importance of Cis-Coordinating Phosphines

  Journal of the American Chemical Society · 2003 · https://doi.org/10.1021/ja029341y

• Single-crystal structure validation with the program PLATON

  Journal of Applied Crystallography · 2003 · https://doi.org/10.1107/s0021889802022112

• End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands: Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry

  Inorganic Chemistry · 2003 · https://doi.org/10.1021/ic034065p

• A “Dendritic Effect” in Homogeneous Catalysis with Carbosilane-Supported Arylnickel(II) Catalysts: Observation of Active-Site Proximity Effects in Atom-Transfer Radical Addition

  Journal of the American Chemical Society · 2000 · https://doi.org/10.1021/ja0026612

• Organoplatinum crystals for gas-triggered switches

  Nature · 2000 · https://doi.org/10.1038/35023107

• Origin of the Bite Angle Effect on Rhodium Diphosphine Catalyzed Hydroformylation

  Organometallics · 2000 · https://doi.org/10.1021/om990734o

• Cyclic Bis-Urea Compounds as Gelators for Organic Solvents

  Chemistry - A European Journal · 1999 · https://doi.org/10.1002/(sici)1521-3765(19990301)5:3<937::aid-chem937>3.0.co;2-0

• Iron Chemistry of a Pentadentate Ligand That Generates a Metastable FeIII−OOH Intermediate

  Inorganic Chemistry · 1999 · https://doi.org/10.1021/ic980983p

• Strong Dimerization of Ureidopyrimidones via Quadruple Hydrogen Bonding

  Journal of the American Chemical Society · 1998 · https://doi.org/10.1021/ja974112a

• Self-Complementarity Achieved through Quadruple Hydrogen Bonding

  Angewandte Chemie International Edition · 1998 · https://doi.org/10.1002/(sici)1521-3773(19980202)37:1/2<75::aid-anie75>3.0.co;2-r

• Hydrogen-Bonded Complexes of Diaminopyridines and Diaminotriazines: Opposite Effect of Acylation on Complex Stabilities

  The Journal of Organic Chemistry · 1996 · https://doi.org/10.1021/jo960612v

• Synthesis and characterization of rigid bidentate nitrogen ligands and some examples of coordination to divalent palladium. X‐ray crystal structures of bis (p‐tolylimino) acenaphthene and methylchloro [bis(o,o′‐diisopropylphenyl‐imino) acenaphthene] palladium (II)

  Recueil des Travaux Chimiques des Pays-Bas · 1994 · https://doi.org/10.1002/recl.19941130204

• NMR study on the coordination behavior of dissymmetric terdentate trinitrogen ligands on methylpalladium(II) compounds

  Inorganic Chemistry · 1993 · https://doi.org/10.1021/ic00077a020

• New neutral and ionic methyl and chloro palladium and platinum complexes containing hemilabile phosphorus-nitrogen ligands. Study of the insertion of carbon monoxide into the metal-methyl bond

  Organometallics · 1992 · https://doi.org/10.1021/om00041a028

• BYPASS: an effective method for the refinement of crystal structures containing disordered solvent regions

  Acta Crystallographica Section A Foundations of Crystallography · 1990 · https://doi.org/10.1107/s0108767389011189

• Dimethyl(N,N,N',N'-tetramethylethanediamine)palladium(II) and dimethyl[1,2-bis(dimethylphosphino)ethane]palladium(II): syntheses, x-ray crystal structures, and thermolysis, oxidative-addition and ligand-exchange reactions

  Organometallics · 1989 · https://doi.org/10.1021/om00114a028

• Synthesis of monomeric permethylyttrocene derivatives. The crystal structures of Cp2*YN(SiMe3)2 and Cp2*YCH(SiMe3)2

  Organometallics · 1986 · https://doi.org/10.1021/om00139a034

Current projects

No projects listed.