Arnold L. Rheingold

Research interests

Publications

• Discovery and Synthesis of a Phosphoramidate Prodrug of a Pyrrolo[2,1-f][triazin-4-amino] Adenine C-Nucleoside (GS-5734) for the Treatment of Ebola and Emerging Viruses

  Journal of Medicinal Chemistry · 2017 · https://doi.org/10.1021/acs.jmedchem.6b01594

• Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry

  Nature Chemistry · 2016 · 10.1038/nchem.2686

• Inducing and quantifying forbidden reactivity with single-molecule polymer mechanochemistry

  Nature Chemistry · 2015 · 10.1038/nchem.2185

• Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis

  Journal of the American Chemical Society · 2014 · 10.1021/ja501252f

• Pd-Catalyzed Enantioselective C–H Iodination: Asymmetric Synthesis of Chiral Diarylmethylamines

  Journal of the American Chemical Society · 2013 · 10.1021/ja408864c

• Synthesis, Luminescence Properties, and Explosives Sensing with 1,1-Tetraphenylsilole- and 1,1-Silafluorene-vinylene Polymers

  Chemistry of Materials · 2007 · 10.1021/cm702299g

• Comparative in Vivo Stability of Copper-64-Labeled Cross-Bridged and Conventional Tetraazamacrocyclic Complexes

  Journal of Medicinal Chemistry · 2004 · https://doi.org/10.1021/jm030383m

• A Linear, O-Coordinated η 1 -CO 2 Bound to Uranium

  Science · 2004 · https://doi.org/10.1126/science.1102602

• Variable character of O—O and M—O bonding in side-on (η 2 ) 1:1 metal complexes of O 2

  Proceedings of the National Academy of Sciences · 2003 · https://doi.org/10.1073/pnas.0535926100

• A Supramolecular Approach to an Allosteric Catalyst

  Journal of the American Chemical Society · 2003 · 10.1021/ja035621h

• Cobalt single-molecule magnet

  Journal of Applied Physics · 2002 · 10.1063/1.1450813

• Mechanistic Studies of the Palladium-Catalyzed Amination of Aryl Halides and the Oxidative Addition of Aryl Bromides to Pd(BINAP)2 and Pd(DPPF)2: An Unusual Case of Zero-Order Kinetic Behavior and Product Inhibition

  Journal of the American Chemical Society · 2000 · 10.1021/ja9944599

• Syntheses of tris(pyrazolyl)methane ligands and {[tris(pyrazolyl)methane]Mn(CO)3}SO3CF3 complexes: comparison of ligand donor properties

  Journal of Organometallic Chemistry · 2000 · 10.1016/s0022-328x(00)00290-4

• Reduced Anionic Mn12Molecules with Half-Integer Ground States as Single-Molecule Magnets

  Inorganic Chemistry · 1999 · https://doi.org/10.1021/ic990613g

• A Functional Model for O-O Bond Formation by the O 2 -Evolving Complex in Photosystem II

  Science · 1999 · https://doi.org/10.1126/science.283.5407.1524

• Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers

  Journal of the American Chemical Society · 1999 · 10.1021/ja984321a

• Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp 2 -, and sp 3 -Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation

  Journal of the American Chemical Society · 1998 · 10.1021/ja981428p

• Luminescent transition-metal-containing cyclophanes (“molecular squares”): covalent self-assembly, host-guest studies and preliminary nanoporous materials applications

  Coordination Chemistry Reviews · 1998 · https://doi.org/10.1016/s0010-8545(98)90035-2

• Structure and Magnetic Ordering of MII[N(CN)2]2 (M = Co, Ni)

  Chemistry of Materials · 1998 · 10.1021/cm980321y

• Variable-Temperature Studies of Laser-Initiated 5 T 2 → 1 A 1 Intersystem Crossing in Spin-Crossover Complexes: Empirical Correlations between Activation Parameters and Ligand Structure in a Series of Polypyridyl Ferrous Complexes

  Inorganic Chemistry · 1996 · 10.1021/ic9507880

• A New Intermolecular Interaction: UnconventionalHydrogen Bonds with Element−Hydride Bonds as ProtonAcceptor

  Accounts of Chemical Research · 1996 · https://doi.org/10.1021/ar950150s

• Synthesis of an Organosilicon Dendrimer Containing 324 Si-H Bonds

  Organometallics · 1994 · 10.1021/om00019a026

• An Unusual Type of H.cntdot..cntdot..cntdot.H Interaction: Ir-H.cntdot..cntdot..cntdot.H-O and Ir-H.cntdot..cntdot..cntdot.H-N Hydrogen Bonding and Its Involvement in .sigma.-Bond Metathesis

  Journal of the American Chemical Society · 1994 · 10.1021/ja00103a017

• Bistability in the [CoII(semiquinonate)2] to [CoIII(catecholate)(semiquinonate)] valence-tautomeric conversion

  Journal of the American Chemical Society · 1993 · 10.1021/ja00071a035

• Binuclear manganese(III) complexes of potential biological significance

  Journal of the American Chemical Society · 1987 · 10.1021/ja00239a025

Current projects

No projects listed.