Constantin G. Daniliuc

Research interests

Publications

• Lewis Acid Catalyzed Formal (3+2)‐Cycloaddition of Bicyclo[1.1.0]butanes with Ketenes

  Angewandte Chemie International Edition · 2023 · 10.1002/anie.202304771

• Dearomative ring expansion of thiophenes by bicyclobutane insertion

  Science · 2023 · 10.1126/science.adh9737

• Catalytic Formal [2π+2σ] Cycloaddition of Aldehydes with Bicyclobutanes: Expedient Access to Polysubstituted 2‐Oxabicyclo[2.1.1]hexanes

  Angewandte Chemie International Edition · 2023 · 10.1002/anie.202305043

• ortho -Selective Dearomative [2π + 2σ] Photocycloadditions of Bicyclic Aza-Arenes

  Journal of the American Chemical Society · 2023 · 10.1021/jacs.3c02961

• Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer

  Journal of the American Chemical Society · 2022 · 10.1021/jacs.2c09248

• Intermolecular [2π+2σ]-photocycloaddition enabled by triplet energy transfer

  Nature · 2022 · https://doi.org/10.1038/s41586-022-04636-x

• Photochemical single-step synthesis of β-amino acid derivatives from alkenes and (hetero)arenes

  Nature Chemistry · 2022 · 10.1038/s41557-022-01008-w

• Photochemical intermolecular dearomative cycloaddition of bicyclic azaarenes with alkenes

  Science · 2021 · https://doi.org/10.1126/science.abg0720

• Metal-free photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates

  Nature Catalysis · 2021 · 10.1038/s41929-020-00553-2

• Boron-enabled geometric isomerization of alkenes via selective energy-transfer catalysis

  Science · 2020 · 10.1126/science.abb7235

• Diastereodivergent synthesis of enantioenriched α,β-disubstituted γ-butyrolactones via cooperative N-heterocyclic carbene and Ir catalysis

  Nature Catalysis · 2019 · 10.1038/s41929-019-0387-3

• Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach

  Chem · 2019 · https://doi.org/10.1016/j.chempr.2019.06.004

• Highly Enantioselective [5 + 2] Annulations through Cooperative N-Heterocyclic Carbene (NHC) Organocatalysis and Palladium Catalysis

  Journal of the American Chemical Society · 2018 · 10.1021/jacs.8b00868

• Mechanistic Studies on a Cooperative NHC Organocatalysis/Palladium Catalysis System: Uncovering Significant Lessons for Mixed Chiral Pd(NHC)(PR3) Catalyst Design

  Journal of the American Chemical Society · 2017 · 10.1021/jacs.7b00462

• General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands

  Angewandte Chemie International Edition · 2017 · https://doi.org/10.1002/anie.201611981

• Redox‐Neutral Manganese(I)‐Catalyzed C−H Activation: Traceless Directing Group Enabled Regioselective Annulation

  Angewandte Chemie International Edition · 2017 · 10.1002/anie.201707396

• Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Enantioselective Umpolung Annulations

  Journal of the American Chemical Society · 2016 · https://doi.org/10.1021/jacs.6b04364

• Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)‐Catalyzed Intermolecular Carboamination of Alkenes

  Angewandte Chemie International Edition · 2016 · 10.1002/anie.201608729

• Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction

  Nature Chemistry · 2015 · 10.1038/nchem.2337

• N‐Heterocyclic Carbene Catalyzed Formal [3+2] Annulation Reaction of Enals: An Efficient Enantioselective Access to Spiro‐Heterocycles

  Angewandte Chemie International Edition · 2014 · 10.1002/anie.201405381

• N-Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4 + 3] and [4 + 1] Annulations for the Synthesis of 1,2-Diazepines and Pyrazoles

  Journal of the American Chemical Society · 2014 · 10.1021/ja510737n

• The CH Activation/1,3‐Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by Rh III Catalysis

  Angewandte Chemie International Edition · 2014 · 10.1002/anie.201403782

• N -Aminopyridinium Salts as Precursors for N-Centered Radicals – Direct Amidation of Arenes and Heteroarenes

  Organic Letters · 2014 · https://doi.org/10.1021/ol503338b

• Stereospecific Formal [3+2] Dipolar Cycloaddition of Cyclopropanes with Nitrosoarenes: An Approach to Isoxazolidines

  Angewandte Chemie International Edition · 2014 · 10.1002/anie.201400885

• 6‐Trifluoromethyl‐Phenanthridines through Radical Trifluoromethylation of Isonitriles

  Angewandte Chemie International Edition · 2013 · https://doi.org/10.1002/anie.201306082

• 6-Phosphorylated Phenanthridines from 2-Isocyanobiphenyls via Radical C–P and C–C Bond Formation

  Organic Letters · 2013 · 10.1021/ol403256e

Current projects

No projects listed.