Herbert W. Roesky

Research interests

Publications

• Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature

  Accounts of Chemical Research · 2016 · https://doi.org/10.1021/acs.accounts.5b00381

• An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

  Journal of the American Chemical Society · 2016 · https://doi.org/10.1021/jacs.6b00032

• Silicon based radicals, radical ions, diradicals and diradicaloids

  Chemical Society Reviews · 2015 · https://doi.org/10.1039/c5cs00739a

• An Aluminum Hydride That Functions like a Transition‐Metal Catalyst

  Angewandte Chemie International Edition · 2015 · https://doi.org/10.1002/anie.201503304

• A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

  Angewandte Chemie International Edition · 2013 · https://doi.org/10.1002/anie.201208307

• Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom

  Journal of the American Chemical Society · 2013 · https://doi.org/10.1021/ja406112u

• Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block

  Accounts of Chemical Research · 2012 · https://doi.org/10.1021/ar300196u

• Conversion of a Singlet Silylene to a stable Biradical

  Angewandte Chemie International Edition · 2012 · https://doi.org/10.1002/anie.201204487

• Chemistry of functionalized silylenes

  Chemical Science · 2011 · https://doi.org/10.1039/c1sc00757b

• Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

  Accounts of Chemical Research · 2011 · https://doi.org/10.1021/ar2001759

• Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

  Journal of the American Chemical Society · 2009 · https://doi.org/10.1021/ja900880z

• Lewis Base Stabilized Dichlorosilylene

  Angewandte Chemie International Edition · 2009 · https://doi.org/10.1002/anie.200901766

• High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

  Journal of the American Chemical Society · 2009 · https://doi.org/10.1021/ja9091374

• The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

  Organometallics · 2008 · https://doi.org/10.1021/om7007869

• RGe(I)Ge(I)R Compound (R = PhC(NtBu)2) with a Ge−Ge Single Bond and a Comparison with the Gauche Conformation of Hydrazine

  Organometallics · 2008 · https://doi.org/10.1021/om800714f

• Stable Monomeric Germanium( II ) and Tin( II ) Compounds with Terminal Hydrides

  Angewandte Chemie International Edition · 2006 · https://doi.org/10.1002/anie.200504337

• Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene

  Angewandte Chemie International Edition · 2006 · https://doi.org/10.1002/anie.200600647

• Transformations of Molecules and Secondary Building Units to Materials: A Bottom-Up Approach

  Accounts of Chemical Research · 2004 · https://doi.org/10.1021/ar040083e

• The interplay of coordinative, hydrogen bonding and π–π stacking interactions in sustaining supramolecular solid-state architectures.

  Coordination Chemistry Reviews · 2003 · https://doi.org/10.1016/s0010-8545(02)00218-7

• Synthesis and Structures of Monomeric Divalent Germanium and Tin Compounds Containing a Bulky Diketiminato Ligand

  Organometallics · 2001 · https://doi.org/10.1021/om000871h

• Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene

  Angewandte Chemie International Edition · 2000 · https://doi.org/10.1002/1521-3773(20001201)39:23<4274::aid-anie4274>3.0.co;2-k

• Molecular Phosphonate Cages: Model Compounds and Starting Materials for Phosphate Materials

  Accounts of Chemical Research · 1998 · https://doi.org/10.1021/ar980040w

• Organometallic Fluorides: Compounds Containing Carbon−Metal−Fluorine Fragments of d-Block Metals

  Chemical Reviews · 1997 · https://doi.org/10.1021/cr960365v

• Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols, and Trisilanols

  Chemical Reviews · 1996 · https://doi.org/10.1021/cr9500747

• Discrete Silanetriols: Building Blocks for Three-Dimensional Metallasiloxanes

  Accounts of Chemical Research · 1996 · https://doi.org/10.1021/ar950154x

• A Simple Synthesis of [(Cp*Al)4] and Its Conversion to the Heterocubanes [(Cp*AlSe)4] and [(Cp*AlTe)4] (Cp* = η5‐C5(CH3)5)

  Angewandte Chemie International Edition in English · 1993 · https://doi.org/10.1002/anie.199317291

Current projects

No projects listed.