Thomas Weyhermüller

Research interests

Publications

• Identification of a spin-coupled Mo( iii ) in the nitrogenase iron–molybdenum cofactor

  Chemical Science · 2014 · 10.1039/c4sc00337c

• Experimental Fingerprints for Redox-Active Terpyridine in [Cr(tpy)2](PF6)n (n = 3–0), and the Remarkable Electronic Structure of [Cr(tpy)2]1–

  Inorganic Chemistry · 2012 · 10.1021/ic2027219

• Electronic and Molecular Structures of the Members of the Electron Transfer Series [Cr(tbpy)3]n (n = 3+, 2+, 1+, 0): An X-ray Absorption Spectroscopic and Density Functional Theoretical Study

  Inorganic Chemistry · 2011 · 10.1021/ic201123x

• Neutral Bis(α-iminopyridine)metal Complexes of the First-Row Transition Ions (Cr, Mn, Fe, Co, Ni, Zn) and Their Monocationic Analogues: Mixed Valency Involving a Redox Noninnocent Ligand System

  Journal of the American Chemical Society · 2008 · 10.1021/ja710663n

• A Tetracopper(II)-Tetraradical Cuboidal Core and Its Reactivity as a Functional Model of Phenoxazinone Synthase

  Inorganic Chemistry · 2007 · 10.1021/ic7012599

• Cobalt complexes of terpyridine ligand: Crystal structure and photocleavage of DNA

  Journal of Inorganic Biochemistry · 2006 · 10.1016/j.jinorgbio.2006.11.002

• Property‐Oriented Rational Design of Single‐Molecule Magnets: A C3‐Symmetric Mn6Cr Complex based on Three Molecular Building Blocks with a Spin Ground State of St=21/2

  Angewandte Chemie International Edition · 2006 · 10.1002/anie.200600712

• Oxidative DNA cleavage mediated by a new copper (II) terpyridine complex: Crystal structure and DNA binding studies

  Journal of Inorganic Biochemistry · 2005 · 10.1016/j.jinorgbio.2005.08.011

• The Electronic Structure of the Isoelectronic, Square-Planar Complexes [FeII(L)2]2-and [CoIII(LBu)2]-(L2-and (LBu)2-= Benzene-1,2-dithiolates): An Experimental and Density Functional Theoretical Study

  Journal of the American Chemical Society · 2005 · 10.1021/ja042803i

• Electronic Structure of Square Planar Bis(benzene-1,2-dithiolato)metal Complexes [M(L) 2 ] z ( z = 2−, 1−, 0; M = Ni, Pd, Pt, Cu, Au): An Experimental, Density Functional, and Correlated ab Initio Study

  Inorganic Chemistry · 2005 · 10.1021/ic0507565

• Complex Formation of ICL670 and Related Ligands with FeIII and FeII

  European Journal of Inorganic Chemistry · 2004 · 10.1002/ejic.200400363

• Molecular and Electronic Structure of Four‐ and Five‐Coordinate Cobalt Complexes Containing Two o‐Phenylenediamine‐ or Two o‐Aminophenol‐Type Ligands at Various Oxidation Levels: An Experimental, Density Functional, and Correlated ab initio Study

  Chemistry - A European Journal · 2004 · 10.1002/chem.200400850

• Structural, Spectroscopic, and Computational Study of an Octahedral, Non-Heme {Fe−NO}6-8 Series: [Fe(NO)(cyclam-ac)]2+/+/0

  Journal of the American Chemical Society · 2004 · 10.1021/ja030645+

• Dinuclear and mononuclear manganese( iv )-radical complexes and their catalytic catecholase activity

  Dalton Transactions · 2004 · 10.1039/b410842f

• Molecular and Electronic Structures of Bis-( o -diiminobenzosemiquinonato)metal(II) Complexes (Ni, Pd, Pt), Their Monocations and -Anions, and of Dimeric Dications Containing Weak Metal−Metal Bonds

  Journal of the American Chemical Society · 2003 · 10.1021/ja030123u

• Molecular and Electronic Structure of Octahedral o-Aminophenolato and o-Iminobenzosemiquinonato Complexes of V(V), Cr(III), Fe(III), and Co(III). Experimental Determination of Oxidation Levels of Ligands and Metal Ions

  Inorganic Chemistry · 2001 · 10.1021/ic010106a

• Experimental Evidence for the Noninnocence of o-Aminothiophenolates: Coordination Chemistry of o-Iminothionebenzosemiquinonate(1-) π-Radicals with Ni(II), Pd(II), Pt(II)

  Journal of the American Chemical Society · 2001 · 10.1021/ja011155p

• Electronic Structure of Bis( o -iminobenzosemiquinonato)metal Complexes (Cu, Ni, Pd). The Art of Establishing Physical Oxidation States in Transition-Metal Complexes Containing Radical Ligands

  Journal of the American Chemical Society · 2001 · https://doi.org/10.1021/ja003831d

• Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+ and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in Water/Acetone Mixtures

  Inorganic Chemistry · 2000 · https://doi.org/10.1021/ic0005238

• Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)

  Inorganic Chemistry · 2000 · https://doi.org/10.1021/ic000113j

• The Electronic Structures of an Isostructural Series of Octahedral Nitrosyliron Complexes {Fe−NO}6,7,8Elucidated by Mössbauer Spectroscopy

  Journal of the American Chemical Society · 2000 · 10.1021/ja994161i

• Photolysis ofcis- andtrans-[FeIII(cyclam)(N3)2]+Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species

  Journal of the American Chemical Society · 1999 · 10.1021/ja983454t

• Aerobic Oxidation of Primary Alcohols by a New Mononuclear CuII-Radical Catalyst

  Angewandte Chemie International Edition · 1999 · https://doi.org/10.1002/(sici)1521-3773(19990419)38:8<1095::aid-anie1095>3.0.co;2-i

• Aerobic Oxidation of Primary Alcohols (Including Methanol) by Copper(II)− and Zinc(II)−Phenoxyl Radical Catalysts

  Journal of the American Chemical Society · 1999 · https://doi.org/10.1021/ja991481t

• Phenoxyl Radical Complexes of Zinc(II)

  Journal of the American Chemical Society · 1997 · 10.1021/ja970417d

Current projects

No projects listed.