Bas de Bruin

Research interests

Publications

• Transition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere

  Chemical Reviews · 2022 · 10.1021/acs.chemrev.1c00862

• Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes

  ACS Catalysis · 2020 · 10.1021/acscatal.0c00961

• Nitrene Radical Intermediates in Catalytic Synthesis

  Chemistry - A European Journal · 2017 · 10.1002/chem.201702537

• Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles

  Chemistry - A European Journal · 2017 · 10.1002/chem.201700358

• Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

  Journal of the American Chemical Society · 2017 · https://doi.org/10.1021/jacs.7b00270

• Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst

  Science · 2015 · 10.1126/science.aaa8938

• Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

  Journal of the American Chemical Society · 2015 · 10.1021/jacs.5b01197

• Catalytic Synthesis of 2H-Chromenes

  ACS Catalysis · 2015 · 10.1021/acscatal.5b00026

• Transition metal catalysis in confined spaces

  Chemical Society Reviews · 2014 · https://doi.org/10.1039/c4cs00192c

• Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

  Journal of the American Chemical Society · 2014 · 10.1021/ja502164f

• Synthesis of functional ‘polyolefins’: state of the art and remaining challenges

  Chemical Society Reviews · 2013 · https://doi.org/10.1039/c3cs60032g

• Metalloradical Approach to 2 H -Chromenes

  Journal of the American Chemical Society · 2013 · 10.1021/ja4111336

• Complexes with Nitrogen‐Centered Radical Ligands: Classification, Spectroscopic Features, Reactivity, and Catalytic Applications

  Angewandte Chemie International Edition · 2013 · https://doi.org/10.1002/anie.201301487

• Closed-shell and open-shell square-planar iridium nitrido complexes

  Nature Chemistry · 2012 · 10.1038/nchem.1368

• Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

  ACS Catalysis · 2012 · 10.1021/cs200660v

• Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

  Journal of the American Chemical Society · 2011 · 10.1021/ja203434c

• Mechanism of Cobalt(II) Porphyrin-Catalyzed C–H Amination with Organic Azides: Radical Nature and H-Atom Abstraction Ability of the Key Cobalt(III)–Nitrene Intermediates

  Journal of the American Chemical Society · 2011 · 10.1021/ja204800a

• Redox Noninnocence of Carbene Ligands: Carbene Radicals in (Catalytic) C−C Bond Formation

  Inorganic Chemistry · 2011 · 10.1021/ic200043a

• Ligands that Store and Release Electrons during Catalysis

  Angewandte Chemie International Edition · 2011 · https://doi.org/10.1002/anie.201006778

• Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes

  Angewandte Chemie International Edition · 2011 · 10.1002/anie.201005173

• ‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

  Journal of the American Chemical Society · 2010 · https://doi.org/10.1021/ja103768r

• C1 polymerisation and related C–C bond forming ‘carbeneinsertion’ reactions

  Chemical Society Reviews · 2009 · 10.1039/b911333a

• Rhodium-Mediated Stereoselective Polymerization of “Carbenes”

  Journal of the American Chemical Society · 2006 · 10.1021/ja058722j

• Formation of a Paramagnetic Al Complex and Extrusion of Fe during the Reaction of (Diiminepyridine)Fe with AlR3 (R = Me, Et)

  Journal of the American Chemical Society · 2005 · 10.1021/ja056135s

• Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML2](PF6)n (n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)

  Inorganic Chemistry · 2000 · 10.1021/ic000113j

Current projects

No projects listed.