Alessandro Prescimone

Research interests

Publications

• Photoredox-active Cr(0) luminophores featuring photophysical properties competitive with Ru(II) and Os(II) complexes

  Nature Chemistry · 2023 · 10.1038/s41557-023-01297-9

• Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel(II) Complexes

  Journal of the American Chemical Society · 2022 · 10.1021/jacs.2c08838

• Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop**

  Angewandte Chemie International Edition · 2022 · 10.1002/anie.202208591

• Cobalt(III) Carbene Complex with an Electronic Excited-State Structure Similar to Cyclometalated Iridium(III) Compounds

  Journal of the American Chemical Society · 2022 · 10.1021/jacs.2c02592

• A Near‐Infrared‐II Emissive Chromium(III) Complex

  Angewandte Chemie International Edition · 2021 · 10.1002/anie.202106398

• Photostable Ruthenium(II) Isocyanoborato Luminophores and Their Use in Energy Transfer and Photoredox Catalysis

  JACS Au · 2021 · 10.1021/jacsau.1c00137

• Four-Step Access to the Sesquiterpene Natural Product Presilphiperfolan-1β-ol and Unnatural Derivatives via Supramolecular Catalysis

  Journal of the American Chemical Society · 2020 · 10.1021/jacs.0c01464

• Ligand-Controlled Regiodivergent Palladium-Catalyzed Hydrogermylation of Ynamides

  Journal of the American Chemical Society · 2020 · 10.1021/jacs.0c03556

• Luminescent copper( i ) complexes with bisphosphane and halogen-substituted 2,2′-bipyridine ligands

  Dalton Transactions · 2018 · 10.1039/c8dt01338a

• Highly Stable Red-Light-Emitting Electrochemical Cells

  Journal of the American Chemical Society · 2017 · 10.1021/jacs.6b13311

• A Tris(diisocyanide)chromium(0) Complex Is a Luminescent Analog of Fe(2,2′-Bipyridine)32+

  Journal of the American Chemical Society · 2017 · 10.1021/jacs.6b11803

• Configurational Stability of [5]Helicenes

  Organic Letters · 2017 · 10.1021/acs.orglett.7b01461

• Shine bright or live long: substituent effects in [Cu(N^N)(P^P)] + -based light-emitting electrochemical cells where N^N is a 6-substituted 2,2′-bipyridine

  Journal of Materials Chemistry C · 2016 · 10.1039/c5tc03725e

• A Molybdenum(0) Isocyanide Analogue of Ru(2,2′‐Bipyridine)32+: A Strong Reductant for Photoredox Catalysis

  Angewandte Chemie International Edition · 2016 · 10.1002/anie.201605571

• Studies on bifunctional Fe( ii )-triazole spin crossover nanoparticles: time-dependent luminescence, surface grafting and the effect of a silica shell and hydrostatic pressure on the magnetic properties

  Journal of Materials Chemistry C · 2015 · 10.1039/c5tc00685f

• Exceptionally long-lived light-emitting electrochemical cells: multiple intra-cation π-stacking interactions in [Ir(C^N) 2 (N^N)][PF 6 ] emitters

  Chemical Science · 2015 · 10.1039/c4sc03942d

• [Cu(bpy)(P^P)] + containing light-emitting electrochemical cells: improving performance through simple substitution

  Dalton Transactions · 2014 · 10.1039/c4dt02847c

• A Mixed‐Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands

  Angewandte Chemie · 2011 · 10.1002/ange.201102727

• A Mixed‐Valence Manganese Cubane Trapped by Inequivalent Trilacunary Polyoxometalate Ligands

  Angewandte Chemie International Edition · 2011 · 10.1002/anie.201102727

• 1D chains of Mn6 single-molecule magnets

  Chemical Communications · 2009 · 10.1039/b900743a

• [Mn6] under Pressure: A Combined Crystallographic and Magnetic Study

  Angewandte Chemie International Edition · 2008 · 10.1002/anie.200705819

• The Contrasting Chemistry and Cancer Cell Cytotoxicity of Bipyridine and Bipyridinediol Ruthenium(II) Arene Complexes

  Inorganic Chemistry · 2008 · 10.1021/ic801361m

• Chloro Half-Sandwich Osmium(II) Complexes: Influence of Chelated N,N-Ligands on Hydrolysis, Guanine Binding, and Cytotoxicity

  Inorganic Chemistry · 2007 · 10.1021/ic062350d

• Spin Switching via Targeted Structural Distortion

  Journal of the American Chemical Society · 2007 · 10.1021/ja070411g

• High-Spin M2+ Carboxylate Triangles from the Microwave

  Inorganic Chemistry · 2006 · 10.1021/ic061035o

Current projects

No projects listed.