Pablo Espinet

Research interests

Publications

• The Stille Reaction, 38 Years Later

  ACS Catalysis · 2015 · https://doi.org/10.1021/acscatal.5b00448

• Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for CC Coupling and Other Reactions

  Chemistry - A European Journal · 2012 · 10.1002/chem.201102888

• Unlikeliness of Pd-Free Gold(I)-Catalyzed Sonogashira Coupling Reactions

  Organic Letters · 2010 · https://doi.org/10.1021/ol101012n

• Nitrogen Acyclic Gold(I) Carbenes: Excellent and Easily Accessible Catalysts in Reactions of 1,6-Enynes

  Organometallics · 2010 · 10.1021/om901026m

• C−C Reductive Elimination in Palladium Complexes, and the Role of Coupling Additives. A DFT Study Supported by Experiment

  Journal of the American Chemical Society · 2009 · 10.1021/ja808036j

• Efficient Synthesis of Chiral 1,1′‐Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids

  Chemistry - A European Journal · 2006 · 10.1002/chem.200600616

• The Mechanisms of the Stille Reaction

  Angewandte Chemie International Edition · 2004 · https://doi.org/10.1002/anie.200300638

• Die Mechanismen der Stille‐Reaktion

  Angewandte Chemie · 2004 · 10.1002/ange.200300638

• A Warning on the Use of Radical Traps as a Test for Radical Mechanisms: They React with Palladium Hydrido Complexes

  Journal of the American Chemical Society · 2002 · 10.1021/ja0271126

• Mechanism of the Stille Reaction. 2. Couplings of Aryl Triflates with Vinyltributyltin. Observation of Intermediates. A More Comprehensive Scheme

  Journal of the American Chemical Society · 2000 · 10.1021/ja001511o

• Phosphine-pyridyl and related ligands in synthesis and catalysis

  Coordination Chemistry Reviews · 1999 · https://doi.org/10.1016/s0010-8545(99)00140-x

• On the Configuration Resulting from Oxidative Addition of RX to Pd(PPh3)4 and the Mechanism of the cis-to-trans Isomerization of [PdRX(PPh3)2] Complexes (R = Aryl, X = Halide)

  Organometallics · 1998 · 10.1021/om9709502

• Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3 Catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = Vinyl, 4-Methoxyphenyl; L = AsPh3)

  Journal of the American Chemical Society · 1998 · 10.1021/ja9742388

• Transition metal liquid crystals: advanced materials within the reach of the coordination chemist

  Coordination Chemistry Reviews · 1992 · https://doi.org/10.1016/0010-8545(92)80025-m

Current projects

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