Andreas Roodt

Research interests

Publications

• Mechanism of generation of closo -decaborato amidrazones. Intramolecular non-covalent B–H⋯π(Ph) interaction determines stabilization of the configuration around the amidrazone CN bond

  New Journal of Chemistry · 2018 · 10.1039/c8nj01018h

• Luminescent, magnetic and optical properties of ZnO-ZnS nanocomposites

  Physica B Condensed Matter · 2016 · 10.1016/j.physb.2016.11.031

• Nucleophilicity of Oximes Based upon Addition to a Nitrilium closo-Decaborate Cluster

  Organometallics · 2016 · 10.1021/acs.organomet.6b00678

• Ethylene Tri- and Tetramerization: a Steric Parameter Selectivity Switch from X-ray Crystallography and Computational Analysis

  Inorganic Chemistry · 2013 · 10.1021/ic302578a

• Coordinated Aqua vs Methanol Substitution Kinetics in fac -Re(I) Tricarbonyl Tropolonato Complexes

  Inorganic Chemistry · 2012 · 10.1021/ic301891u

• Structure/reactivity relationships and mechanism from X-ray data and spectroscopic kinetic analysis

  Crystallography Reviews · 2011 · 10.1080/0889311x.2011.593032

• Tuning the Reactivity in Classic Low-Spin d6 Rhenium(I) Tricarbonyl Radiopharmaceutical Synthon by Selective Bidentate Ligand Variation (L,L′-Bid; L,L′= N,N′, N,O, and O,O′ Donor Atom Sets) in fac-[Re(CO)3(L,L′-Bid)(MeOH)]n Complexes

  Inorganic Chemistry · 2011 · 10.1021/ic2013792

• Steric vs. electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium(i) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl [PR3 = PPh3, PPh2Cy, PPhCy2 and PCy3]

  Dalton Transactions · 2010 · 10.1039/b922083f

• Mechanisms of the CO2 Insertion into (PCP) Palladium Allyl and Methyl σ-Bonds. A Kinetic and Computational Study

  Organometallics · 2010 · 10.1021/om100325v

• Kinetic study of the oxidative addition reaction between methyl iodide and [Rh(FcCOCHCOCF3)(CO)(PPh3)]: Structure of [Rh(FcCOCHCOCF3)(CO)(PPh3)(CH3)(I)]

  Polyhedron · 2007 · 10.1016/j.poly.2007.07.004

• Rapid phosphorus( iii ) ligand evaluation utilising potassium selenocyanate

  Dalton Transactions · 2007 · 10.1039/b712782k

• Borate Esters as Alternative Acid Promoters in the Palladium‐Catalyzed Methoxycarbonylation of Ethylene

  Angewandte Chemie International Edition · 2007 · 10.1002/anie.200603751

• Rhodium hydride formation in the presence of a bulky monophosphite ligand: a spectroscopic and solid-state investigation

  Dalton Transactions · 2005 · 10.1039/b416917d

• Synthesis, crystal structure and hydroformylation activity of triphenylphosphite modified cobalt catalysts

  Dalton Transactions · 2004 · 10.1039/b403033h

• Structure and solution behaviour of rhodium(I) Vaska-type complexes for correlation of steric and electronic properties of tertiary phosphine ligands

  Coordination Chemistry Reviews · 2003 · 10.1016/s0010-8545(03)00069-9

• Quantifying the electronic cis effect of phosphine, arsine and stibine ligands by use of rhodium(I) Vaska-type complexes

  Inorganica Chimica Acta · 2003 · 10.1016/s0020-1693(03)00436-5

• Steric effects induced by ferrocenyl in tertiary organophosphines: crystal structure of trans-chloromethylbis(ferrocenyldiphenylphosphine)palladium(II) benzene disolvate

  Inorganica Chimica Acta · 2000 · 10.1016/s0020-1693(00)00041-4

• Synthesis, characterisation and coordination chemistry of novel chiral N,N-dialkyl-N ′-menthyloxycarbonylthioureas. Crystal and molecular structures of N,N-diethyl-N ′-(−)-(3R)-menthyloxycarbonylthiourea and cis-(S,S)-[Pt(L)Cl(DMSO)] [where HL = N-(+)-(3R)-menthyloxycarbonyl-N′-morpholinothiourea or N-benzoyl-N′,N′-diethylthiourea]

  Journal of the Chemical Society Dalton Transactions · 2000 · 10.1039/b007589m

• Chiral and achiral platinum(II) complexes for potential use as chemotherapeutic agents: crystal and molecular structures of cis-[Pt(L1)2] and [Pt(L1)Cl(MPSO)] [HL1 = N,N-diethyl-N ′-benzoylthiourea]

  Journal of the Chemical Society Dalton Transactions · 2000 · 10.1039/a908985c

• Reaction Mechanism for Olefin Exchange at Chloro Ethene Complexes of Platinum(II)

  Inorganic Chemistry · 1999 · 10.1021/ic981020t

• Structural correlation between Rh-P and Rh-C bond distances vs. 31P and 13C NMR parameters in monocarbonylphosphinerhodium(I) complexes: Crystal structure of (methyl 2-(amino)-1-cyclopentene-1-dithio arboxylato-κN, κS)-carbonyl(triphenylphosphine) rhodium(I)

  Journal of Organometallic Chemistry · 1997 · 10.1016/s0022-328x(96)06670-3

• Unprecedented N,S,O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H2L2) bridging two rhodium(I) centres: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(μ-L2-κN′∶κO,S)Rh(PPh3)(CO)]

  Journal of the Chemical Society Dalton Transactions · 1997 · 10.1039/a705887j

• Octacyano and Oxo- and Nitridotetracyano Complexes of Second and Third Series Early Transition Metals

  Advances in inorganic chemistry · 1993 · 10.1016/s0898-8838(08)60185-3

• Kinetic and structural studies on the oxotetracyanotechnetate(V) core: protonation and ligation of dioxotetracyanotechnetate(V) ions and crystal structure of 2,2'-bipyridinium trans-oxothiocyanatotetracyanotechnetate(V)

  Inorganic Chemistry · 1992 · 10.1021/ic00032a030

• Mechanism for the oxidative addition of lodomethane to carbonyl(N-hydroxy-N-nitrosobenzenaminato-O,O′)triarylphosphinerhodium(I) complexes and crystal structure of [Rh(cupf)(CO)(CH3)(1)(PPh3)]

  Inorganica Chimica Acta · 1987 · 10.1016/s0020-1693(00)84691-5

Current projects

No projects listed.