Manuel G. Basallote

Research interests

Publications

• Catalytic Hydrogenation of Azobenzene in the Presence of a Cuboidal Mo 3 S 4 Cluster via an Uncommon Sulfur-Based H 2 Activation Mechanism

  ACS Catalysis · 2020 · 10.1021/acscatal.0c05299

• Kinetic Analysis and Mechanism of the Hydrolytic Degradation of Squaramides and Squaramic Acids

  The Journal of Organic Chemistry · 2017 · 10.1021/acs.joc.6b02963

• Acid‐Triggered O−O Bond Heterolysis of a Nonheme FeIII(OOH) Species for the Stereospecific Hydroxylation of Strong C−H Bonds

  Chemistry - A European Journal · 2017 · 10.1002/chem.201704851

• Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species

  Angewandte Chemie International Edition · 2016 · 10.1002/anie.201601396

• Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention

  Journal of the American Chemical Society · 2015 · 10.1021/jacs.5b09904

• Speciation-controlled incipient wetness impregnation: A rational synthetic approach to prepare sub-nanosized and highly active ceria–zirconia supported gold catalysts

  Journal of Catalysis · 2014 · 10.1016/j.jcat.2014.07.001

• Water-Soluble Mo3S4 Clusters Bearing Hydroxypropyl Diphosphine Ligands: Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions

  Inorganic Chemistry · 2012 · 10.1021/ic300517g

• Hydrogen and Copper Ion Induced Molecular Reorganizations in Two New Scorpiand-Like Ligands Appended with Pyridine Rings

  Inorganic Chemistry · 2010 · 10.1021/ic100609h

• Chiral [Mo3S4H3(diphosphine)3]+ Hydrido Clusters and Study of the Effect of the Metal Atom on the Kinetics of the Acid-Assisted Substitution of the Coordinated Hydride: Mo vs W

  Inorganic Chemistry · 2010 · 10.1021/ic100381u

• Synthesis, Reactivity, and Kinetics of Substitution in W3PdSe4Cuboidal Clusters. A Reexamination of the Kinetics of Substitution of the Related W3S4Cluster with Thiocyanate

  Inorganic Chemistry · 2009 · 10.1021/ic802150x

• Hydrogen and Copper Ion-Induced Molecular Reorganizations in Scorpionand-like Ligands. A Potentiometric, Mechanistic, and Solid-State Study

  Inorganic Chemistry · 2007 · 10.1021/ic700643n

• Crucial Role of Anions on the Deprotonation of the Cationic Dihydrogen Complex trans -[FeH(η 2 -H 2 )(dppe) 2 ] +

  Journal of the American Chemical Society · 2007 · 10.1021/ja070939l

• Synthesis, Crystal Structure, Aqueous Speciation, and Kinetics of Substitution Reactions in a Water-Soluble Mo3S4 Cluster Bearing Hydroxymethyl Diphosphine Ligands

  Inorganic Chemistry · 2007 · 10.1021/ic701082p

• The Structure of ([W3Q4X3(dmpe)3]+, Y-) Ion Pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH2PMe2) in Dichloromethane Solution and the Effect of Ion-Pairing on the Kinetics of Proton Transfer to the Hydride Cluster [W3S4H3(dmpe)3]+

  Inorganic Chemistry · 2006 · 10.1021/ic0520770

• New Insights into the Mechanism of Proton Transfer to Hydride Complexes: Kinetic and Theoretical Evidence Showing the Existence of Competitive Pathways for Protonation of the Cluster [W 3 S 4 H 3 (dmpe) 3 ] + with Acids

  Chemistry - A European Journal · 2005 · 10.1002/chem.200500695

• Mechanism of the Reaction of the [W 3 S 4 H 3 (dmpe) 3 ] + Cluster with Acids: Evidence for the Acid‐Promoted Substitution of Coordinated Hydrides and the Effect of the Attacking Species on the Kinetics of Protonation of the Metal‐Hydride Bonds

  Chemistry - A European Journal · 2004 · 10.1002/chem.200305376

• Synthesis and structure of the incomplete cuboidal clusters [W 3 Se 4 H 3 (dmpe) 3 ] + , [W 3 Se 4 H 3−x (OH) x (dmpe) 3 ] + and [W 3 Se 4 (OH) 3 (dmpe) 3 ] + , and the mechanism of the acid-assisted substitution of the coordinated hydrides

  Dalton Transactions · 2004 · 10.1039/b315841a

• The Effect of the “Inert” Counteranions in the Deprotonation of the Dihydrogen Complex trans-[FeH(η2-H2)(dppe)2]+: Kinetic and Theoretical Studies

  Journal of the American Chemical Society · 2004 · 10.1021/ja039844j

• Kinetics of formation of dihydrogen complexes: protonation of cis-[FeH2{P(CH2CH2PPh2)3} with acids in tetrahydrofuran †

  Journal of the Chemical Society Dalton Transactions · 1998 · 10.1039/a707491c

• Unexpected Mechanism for Substitution of Coordinated Dihydrogen in trans-[FeH(H2)(DPPE)2]+

  Inorganic Chemistry · 1998 · 10.1021/ic970493h

• Kinetics of protonation of cis-[FeH2(dppe)2]: formation of the dihydrogen complex trans-[FeH(H2)(dppe)2]+ (dppe = Ph2PCH2CH2PPh2)

  Journal of the Chemical Society Dalton Transactions · 1998 · 10.1039/a800916c

• New multidentate ligands. 29. Stabilities of metal complexes of the binucleating macrocyclic ligand BISBAMP and dioxygen affinity of its dinuclear cobalt(II) complex

  Inorganic Chemistry · 1988 · 10.1021/ic00296a025

Current projects

No projects listed.